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         <PDBx:type>L-peptide linking</PDBx:type>
      </PDBx:chem_comp>
      <PDBx:chem_comp id="CYS">
         <PDBx:formula>C3 H7 N O2 S</PDBx:formula>
         <PDBx:formula_weight>121.158</PDBx:formula_weight>
         <PDBx:mon_nstd_flag>y</PDBx:mon_nstd_flag>
         <PDBx:name>CYSTEINE</PDBx:name>
         <PDBx:type>L-peptide linking</PDBx:type>
      </PDBx:chem_comp>
      <PDBx:chem_comp id="DTR">
         <PDBx:formula>C11 H12 N2 O2</PDBx:formula>
         <PDBx:formula_weight>204.225</PDBx:formula_weight>
         <PDBx:mon_nstd_flag xsi:nil="true" />
         <PDBx:name>D-TRYPTOPHAN</PDBx:name>
         <PDBx:type>D-peptide linking</PDBx:type>
      </PDBx:chem_comp>
      <PDBx:chem_comp id="GLN">
         <PDBx:formula>C5 H10 N2 O3</PDBx:formula>
         <PDBx:formula_weight>146.144</PDBx:formula_weight>
         <PDBx:mon_nstd_flag>y</PDBx:mon_nstd_flag>
         <PDBx:name>GLUTAMINE</PDBx:name>
         <PDBx:type>L-peptide linking</PDBx:type>
      </PDBx:chem_comp>
      <PDBx:chem_comp id="GLY">
         <PDBx:formula>C2 H5 N O2</PDBx:formula>
         <PDBx:formula_weight>75.067</PDBx:formula_weight>
         <PDBx:mon_nstd_flag>y</PDBx:mon_nstd_flag>
         <PDBx:name>GLYCINE</PDBx:name>
         <PDBx:type>peptide linking</PDBx:type>
      </PDBx:chem_comp>
      <PDBx:chem_comp id="HYP">
         <PDBx:formula>C5 H9 N O3</PDBx:formula>
         <PDBx:formula_weight>131.130</PDBx:formula_weight>
         <PDBx:mon_nstd_flag>n</PDBx:mon_nstd_flag>
         <PDBx:name>4-HYDROXYPROLINE</PDBx:name>
         <PDBx:pdbx_synonyms>HYDROXYPROLINE</PDBx:pdbx_synonyms>
         <PDBx:type>L-peptide linking</PDBx:type>
      </PDBx:chem_comp>
      <PDBx:chem_comp id="PRO">
         <PDBx:formula>C5 H9 N O2</PDBx:formula>
         <PDBx:formula_weight>115.130</PDBx:formula_weight>
         <PDBx:mon_nstd_flag>y</PDBx:mon_nstd_flag>
         <PDBx:name>PROLINE</PDBx:name>
         <PDBx:type>L-peptide linking</PDBx:type>
      </PDBx:chem_comp>
      <PDBx:chem_comp id="TRP">
         <PDBx:formula>C11 H12 N2 O2</PDBx:formula>
         <PDBx:formula_weight>204.225</PDBx:formula_weight>
         <PDBx:mon_nstd_flag>y</PDBx:mon_nstd_flag>
         <PDBx:name>TRYPTOPHAN</PDBx:name>
         <PDBx:type>L-peptide linking</PDBx:type>
      </PDBx:chem_comp>
   </PDBx:chem_compCategory>
   <PDBx:citationCategory>
      <PDBx:citation id="primary">
         <PDBx:country>US</PDBx:country>
         <PDBx:journal_abbrev>Biochemistry</PDBx:journal_abbrev>
         <PDBx:journal_id_ASTM>BICHAW</PDBx:journal_id_ASTM>
         <PDBx:journal_id_CSD>0033</PDBx:journal_id_CSD>
         <PDBx:journal_id_ISSN>0006-2960</PDBx:journal_id_ISSN>
         <PDBx:journal_volume>39</PDBx:journal_volume>
         <PDBx:page_first>12845</PDBx:page_first>
         <PDBx:page_last>12852</PDBx:page_last>
         <PDBx:pdbx_database_id_DOI>10.1021/bi0010930</PDBx:pdbx_database_id_DOI>
         <PDBx:pdbx_database_id_PubMed>11041849</PDBx:pdbx_database_id_PubMed>
         <PDBx:title>Structures of the contryphan family of cyclic peptides. Role of electrostatic  
interactions in cis-trans isomerism.</PDBx:title>
         <PDBx:year>2000</PDBx:year>
      </PDBx:citation>
   </PDBx:citationCategory>
   <PDBx:citation_authorCategory>
      <PDBx:citation_author citation_id="primary" name="Pallaghy, P.K." ordinal="1"></PDBx:citation_author>
      <PDBx:citation_author citation_id="primary" name="He, W." ordinal="2"></PDBx:citation_author>
      <PDBx:citation_author citation_id="primary" name="Jimenez, E.C." ordinal="3"></PDBx:citation_author>
      <PDBx:citation_author citation_id="primary" name="Olivera, B.M." ordinal="4"></PDBx:citation_author>
      <PDBx:citation_author citation_id="primary" name="Norton, R.S." ordinal="5"></PDBx:citation_author>
   </PDBx:citation_authorCategory>
   <PDBx:database_2Category>
      <PDBx:database_2 database_code="1DFZ" database_id="PDB"></PDBx:database_2>
      <PDBx:database_2 database_code="RCSB010051" database_id="RCSB"></PDBx:database_2>
      <PDBx:database_2 database_code="D_1000010051" database_id="WWPDB"></PDBx:database_2>
   </PDBx:database_2Category>
   <PDBx:database_PDB_matrixCategory>
      <PDBx:database_PDB_matrix entry_id="1DFZ">
         <PDBx:origx11>1.000000</PDBx:origx11>
         <PDBx:origx12>0.000000</PDBx:origx12>
         <PDBx:origx13>0.000000</PDBx:origx13>
         <PDBx:origx21>0.000000</PDBx:origx21>
         <PDBx:origx22>1.000000</PDBx:origx22>
         <PDBx:origx23>0.000000</PDBx:origx23>
         <PDBx:origx31>0.000000</PDBx:origx31>
         <PDBx:origx32>0.000000</PDBx:origx32>
         <PDBx:origx33>1.000000</PDBx:origx33>
         <PDBx:origx_vector1>0.00000</PDBx:origx_vector1>
         <PDBx:origx_vector2>0.00000</PDBx:origx_vector2>
         <PDBx:origx_vector3>0.00000</PDBx:origx_vector3>
      </PDBx:database_PDB_matrix>
   </PDBx:database_PDB_matrixCategory>
   <PDBx:entityCategory>
      <PDBx:entity id="1">
         <PDBx:formula_weight>991.146</PDBx:formula_weight>
         <PDBx:pdbx_description>CONTRYPHAN-SM</PDBx:pdbx_description>
         <PDBx:pdbx_number_of_molecules>1</PDBx:pdbx_number_of_molecules>
         <PDBx:src_method>nat</PDBx:src_method>
         <PDBx:type>polymer</PDBx:type>
      </PDBx:entity>
   </PDBx:entityCategory>
   <PDBx:entity_polyCategory>
      <PDBx:entity_poly entity_id="1">
         <PDBx:nstd_linkage>no</PDBx:nstd_linkage>
         <PDBx:nstd_monomer>yes</PDBx:nstd_monomer>
         <PDBx:pdbx_seq_one_letter_code>GC(HYP)(DTR)QPW(CY3)</PDBx:pdbx_seq_one_letter_code>
         <PDBx:pdbx_seq_one_letter_code_can>GCPWQPWC</PDBx:pdbx_seq_one_letter_code_can>
         <PDBx:pdbx_strand_id>A</PDBx:pdbx_strand_id>
         <PDBx:type>polypeptide(L)</PDBx:type>
      </PDBx:entity_poly>
   </PDBx:entity_polyCategory>
   <PDBx:entity_poly_seqCategory>
      <PDBx:entity_poly_seq entity_id="1" mon_id="GLY" num="1">
         <PDBx:hetero>n</PDBx:hetero>
      </PDBx:entity_poly_seq>
      <PDBx:entity_poly_seq entity_id="1" mon_id="CYS" num="2">
         <PDBx:hetero>n</PDBx:hetero>
      </PDBx:entity_poly_seq>
      <PDBx:entity_poly_seq entity_id="1" mon_id="HYP" num="3">
         <PDBx:hetero>n</PDBx:hetero>
      </PDBx:entity_poly_seq>
      <PDBx:entity_poly_seq entity_id="1" mon_id="DTR" num="4">
         <PDBx:hetero>n</PDBx:hetero>
      </PDBx:entity_poly_seq>
      <PDBx:entity_poly_seq entity_id="1" mon_id="GLN" num="5">
         <PDBx:hetero>n</PDBx:hetero>
      </PDBx:entity_poly_seq>
      <PDBx:entity_poly_seq entity_id="1" mon_id="PRO" num="6">
         <PDBx:hetero>n</PDBx:hetero>
      </PDBx:entity_poly_seq>
      <PDBx:entity_poly_seq entity_id="1" mon_id="TRP" num="7">
         <PDBx:hetero>n</PDBx:hetero>
      </PDBx:entity_poly_seq>
      <PDBx:entity_poly_seq entity_id="1" mon_id="CY3" num="8">
         <PDBx:hetero>n</PDBx:hetero>
      </PDBx:entity_poly_seq>
   </PDBx:entity_poly_seqCategory>
   <PDBx:entity_src_natCategory>
      <PDBx:entity_src_nat entity_id="1" pdbx_src_id="1">
         <PDBx:genus>Conus</PDBx:genus>
         <PDBx:pdbx_alt_source_flag>sample</PDBx:pdbx_alt_source_flag>
         <PDBx:pdbx_ncbi_taxonomy_id>89452</PDBx:pdbx_ncbi_taxonomy_id>
         <PDBx:pdbx_organism_scientific>Conus stercusmuscarum</PDBx:pdbx_organism_scientific>
      </PDBx:entity_src_nat>
   </PDBx:entity_src_natCategory>
   <PDBx:entryCategory>
      <PDBx:entry id="1DFZ"></PDBx:entry>
   </PDBx:entryCategory>
   <PDBx:exptlCategory>
      <PDBx:exptl entry_id="1DFZ" method="SOLUTION NMR">
      </PDBx:exptl>
   </PDBx:exptlCategory>
   <PDBx:pdbx_audit_revision_detailsCategory>
      <PDBx:pdbx_audit_revision_details data_content_type="Structure model" ordinal="1" revision_ordinal="1">
         <PDBx:provider>repository</PDBx:provider>
         <PDBx:type>Initial release</PDBx:type>
      </PDBx:pdbx_audit_revision_details>
   </PDBx:pdbx_audit_revision_detailsCategory>
   <PDBx:pdbx_audit_revision_groupCategory>
      <PDBx:pdbx_audit_revision_group data_content_type="Structure model" ordinal="1" revision_ordinal="2">
         <PDBx:group>Version format compliance</PDBx:group>
      </PDBx:pdbx_audit_revision_group>
      <PDBx:pdbx_audit_revision_group data_content_type="Structure model" ordinal="2" revision_ordinal="3">
         <PDBx:group>Version format compliance</PDBx:group>
      </PDBx:pdbx_audit_revision_group>
   </PDBx:pdbx_audit_revision_groupCategory>
   <PDBx:pdbx_audit_revision_historyCategory>
      <PDBx:pdbx_audit_revision_history data_content_type="Structure model" ordinal="1">
         <PDBx:major_revision>1</PDBx:major_revision>
         <PDBx:minor_revision>0</PDBx:minor_revision>
         <PDBx:revision_date>2002-05-01</PDBx:revision_date>
      </PDBx:pdbx_audit_revision_history>
      <PDBx:pdbx_audit_revision_history data_content_type="Structure model" ordinal="2">
         <PDBx:major_revision>1</PDBx:major_revision>
         <PDBx:minor_revision>1</PDBx:minor_revision>
         <PDBx:revision_date>2008-04-27</PDBx:revision_date>
      </PDBx:pdbx_audit_revision_history>
      <PDBx:pdbx_audit_revision_history data_content_type="Structure model" ordinal="3">
         <PDBx:major_revision>1</PDBx:major_revision>
         <PDBx:minor_revision>2</PDBx:minor_revision>
         <PDBx:revision_date>2011-07-13</PDBx:revision_date>
      </PDBx:pdbx_audit_revision_history>
   </PDBx:pdbx_audit_revision_historyCategory>
   <PDBx:pdbx_database_relatedCategory>
      <PDBx:pdbx_database_related content_type="unspecified" db_id="1DFY" db_name="PDB">
         <PDBx:details>STRUCTURE OF ALTERNATIVE FORM OF CONTRYPHAN-SM (MAJOR FORM - CIS)</PDBx:details>
      </PDBx:pdbx_database_related>
      <PDBx:pdbx_database_related content_type="unspecified" db_id="1DG0" db_name="PDB">
         <PDBx:details>STRUCTURE OF DES[GLY1]-CONTRYPHAN-R</PDBx:details>
      </PDBx:pdbx_database_related>
      <PDBx:pdbx_database_related content_type="unspecified" db_id="1QFB" db_name="PDB">
         <PDBx:details>STRUCTURE OF CONTRYPHAN-R</PDBx:details>
      </PDBx:pdbx_database_related>
   </PDBx:pdbx_database_relatedCategory>
   <PDBx:pdbx_database_statusCategory>
      <PDBx:pdbx_database_status entry_id="1DFZ">
         <PDBx:SG_entry xsi:nil="true" />
         <PDBx:deposit_site>RCSB</PDBx:deposit_site>
         <PDBx:pdb_format_compatible>Y</PDBx:pdb_format_compatible>
         <PDBx:process_site>RCSB</PDBx:process_site>
         <PDBx:recvd_initial_deposition_date>1999-11-22</PDBx:recvd_initial_deposition_date>
         <PDBx:status_code>REL</PDBx:status_code>
         <PDBx:status_code_mr>REL</PDBx:status_code_mr>
      </PDBx:pdbx_database_status>
   </PDBx:pdbx_database_statusCategory>
   <PDBx:pdbx_nmr_ensembleCategory>
      <PDBx:pdbx_nmr_ensemble entry_id="1DFZ">
         <PDBx:conformer_selection_criteria>structures with the lowest energy</PDBx:conformer_selection_criteria>
         <PDBx:conformers_calculated_total_number>200</PDBx:conformers_calculated_total_number>
         <PDBx:conformers_submitted_total_number>20</PDBx:conformers_submitted_total_number>
      </PDBx:pdbx_nmr_ensemble>
   </PDBx:pdbx_nmr_ensembleCategory>
   <PDBx:pdbx_nmr_exptlCategory>
      <PDBx:pdbx_nmr_exptl conditions_id="1" experiment_id="1" solution_id="1">
         <PDBx:type>2D NOESY</PDBx:type>
      </PDBx:pdbx_nmr_exptl>
      <PDBx:pdbx_nmr_exptl conditions_id="1" experiment_id="2" solution_id="1">
         <PDBx:type>DQF-COSY</PDBx:type>
      </PDBx:pdbx_nmr_exptl>
      <PDBx:pdbx_nmr_exptl conditions_id="1" experiment_id="3" solution_id="1">
         <PDBx:type>E-COSY</PDBx:type>
      </PDBx:pdbx_nmr_exptl>
      <PDBx:pdbx_nmr_exptl conditions_id="1" experiment_id="4" solution_id="1">
         <PDBx:type>TOCSY</PDBx:type>
      </PDBx:pdbx_nmr_exptl>
   </PDBx:pdbx_nmr_exptlCategory>
   <PDBx:pdbx_nmr_exptl_sample_conditionsCategory>
      <PDBx:pdbx_nmr_exptl_sample_conditions conditions_id="1">
         <PDBx:ionic_strength>0</PDBx:ionic_strength>
         <PDBx:pH>2.9</PDBx:pH>
         <PDBx:pressure>AMBIENT</PDBx:pressure>
         <PDBx:temperature>278</PDBx:temperature>
         <PDBx:temperature_units>K</PDBx:temperature_units>
      </PDBx:pdbx_nmr_exptl_sample_conditions>
   </PDBx:pdbx_nmr_exptl_sample_conditionsCategory>
   <PDBx:pdbx_nmr_refineCategory>
      <PDBx:pdbx_nmr_refine entry_id="1DFZ" software_ordinal="1">
         <PDBx:details>EM IN CHARMM-19 FORCE-FIELD WITH EXPLICIT BOX OF H2O TREATED WITH PBC</PDBx:details>
         <PDBx:method>SIMULATED ANNEALING &amp; ENERGY MINIMIZATION</PDBx:method>
      </PDBx:pdbx_nmr_refine>
   </PDBx:pdbx_nmr_refineCategory>
   <PDBx:pdbx_nmr_representativeCategory>
      <PDBx:pdbx_nmr_representative entry_id="1DFZ">
         <PDBx:conformer_id>1</PDBx:conformer_id>
         <PDBx:selection_criteria>closest to the average</PDBx:selection_criteria>
      </PDBx:pdbx_nmr_representative>
   </PDBx:pdbx_nmr_representativeCategory>
   <PDBx:pdbx_nmr_sample_detailsCategory>
      <PDBx:pdbx_nmr_sample_details solution_id="1">
         <PDBx:contents>5.0 MM</PDBx:contents>
      </PDBx:pdbx_nmr_sample_details>
   </PDBx:pdbx_nmr_sample_detailsCategory>
   <PDBx:pdbx_nmr_softwareCategory>
      <PDBx:pdbx_nmr_software ordinal="1">
         <PDBx:authors>BRUKER</PDBx:authors>
         <PDBx:classification>collection</PDBx:classification>
         <PDBx:name>XWINNMR</PDBx:name>
         <PDBx:version>1.3</PDBx:version>
      </PDBx:pdbx_nmr_software>
      <PDBx:pdbx_nmr_software ordinal="2">
         <PDBx:authors>ECCLES</PDBx:authors>
         <PDBx:classification>processing</PDBx:classification>
         <PDBx:name>XEASY</PDBx:name>
         <PDBx:version>1.3.13</PDBx:version>
      </PDBx:pdbx_nmr_software>
      <PDBx:pdbx_nmr_software ordinal="3">
         <PDBx:authors>BRUNGER</PDBx:authors>
         <PDBx:classification>refinement</PDBx:classification>
         <PDBx:name>X-PLOR</PDBx:name>
         <PDBx:version>3</PDBx:version>
      </PDBx:pdbx_nmr_software>
   </PDBx:pdbx_nmr_softwareCategory>
   <PDBx:pdbx_nmr_spectrometerCategory>
      <PDBx:pdbx_nmr_spectrometer spectrometer_id="1">
         <PDBx:field_strength>600</PDBx:field_strength>
         <PDBx:manufacturer>Bruker</PDBx:manufacturer>
         <PDBx:model>DRX</PDBx:model>
      </PDBx:pdbx_nmr_spectrometer>
   </PDBx:pdbx_nmr_spectrometerCategory>
   <PDBx:pdbx_poly_seq_schemeCategory>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" mon_id="GLY" seq_id="1">
         <PDBx:auth_mon_id>GLY</PDBx:auth_mon_id>
         <PDBx:auth_seq_num>1</PDBx:auth_seq_num>
         <PDBx:hetero>n</PDBx:hetero>
         <PDBx:ndb_seq_num>1</PDBx:ndb_seq_num>
         <PDBx:pdb_ins_code xsi:nil="true" />
         <PDBx:pdb_mon_id>GLY</PDBx:pdb_mon_id>
         <PDBx:pdb_seq_num>1</PDBx:pdb_seq_num>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" mon_id="CYS" seq_id="2">
         <PDBx:auth_mon_id>CYS</PDBx:auth_mon_id>
         <PDBx:auth_seq_num>2</PDBx:auth_seq_num>
         <PDBx:hetero>n</PDBx:hetero>
         <PDBx:ndb_seq_num>2</PDBx:ndb_seq_num>
         <PDBx:pdb_ins_code xsi:nil="true" />
         <PDBx:pdb_mon_id>CYS</PDBx:pdb_mon_id>
         <PDBx:pdb_seq_num>2</PDBx:pdb_seq_num>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" mon_id="HYP" seq_id="3">
         <PDBx:auth_mon_id>HYP</PDBx:auth_mon_id>
         <PDBx:auth_seq_num>3</PDBx:auth_seq_num>
         <PDBx:hetero>n</PDBx:hetero>
         <PDBx:ndb_seq_num>3</PDBx:ndb_seq_num>
         <PDBx:pdb_ins_code xsi:nil="true" />
         <PDBx:pdb_mon_id>HYP</PDBx:pdb_mon_id>
         <PDBx:pdb_seq_num>3</PDBx:pdb_seq_num>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" mon_id="DTR" seq_id="4">
         <PDBx:auth_mon_id>DTR</PDBx:auth_mon_id>
         <PDBx:auth_seq_num>4</PDBx:auth_seq_num>
         <PDBx:hetero>n</PDBx:hetero>
         <PDBx:ndb_seq_num>4</PDBx:ndb_seq_num>
         <PDBx:pdb_ins_code xsi:nil="true" />
         <PDBx:pdb_mon_id>DTR</PDBx:pdb_mon_id>
         <PDBx:pdb_seq_num>4</PDBx:pdb_seq_num>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" mon_id="GLN" seq_id="5">
         <PDBx:auth_mon_id>GLN</PDBx:auth_mon_id>
         <PDBx:auth_seq_num>5</PDBx:auth_seq_num>
         <PDBx:hetero>n</PDBx:hetero>
         <PDBx:ndb_seq_num>5</PDBx:ndb_seq_num>
         <PDBx:pdb_ins_code xsi:nil="true" />
         <PDBx:pdb_mon_id>GLN</PDBx:pdb_mon_id>
         <PDBx:pdb_seq_num>5</PDBx:pdb_seq_num>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" mon_id="PRO" seq_id="6">
         <PDBx:auth_mon_id>PRO</PDBx:auth_mon_id>
         <PDBx:auth_seq_num>6</PDBx:auth_seq_num>
         <PDBx:hetero>n</PDBx:hetero>
         <PDBx:ndb_seq_num>6</PDBx:ndb_seq_num>
         <PDBx:pdb_ins_code xsi:nil="true" />
         <PDBx:pdb_mon_id>PRO</PDBx:pdb_mon_id>
         <PDBx:pdb_seq_num>6</PDBx:pdb_seq_num>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" mon_id="TRP" seq_id="7">
         <PDBx:auth_mon_id>TRP</PDBx:auth_mon_id>
         <PDBx:auth_seq_num>7</PDBx:auth_seq_num>
         <PDBx:hetero>n</PDBx:hetero>
         <PDBx:ndb_seq_num>7</PDBx:ndb_seq_num>
         <PDBx:pdb_ins_code xsi:nil="true" />
         <PDBx:pdb_mon_id>TRP</PDBx:pdb_mon_id>
         <PDBx:pdb_seq_num>7</PDBx:pdb_seq_num>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
      <PDBx:pdbx_poly_seq_scheme asym_id="A" entity_id="1" mon_id="CY3" seq_id="8">
         <PDBx:auth_mon_id>CY3</PDBx:auth_mon_id>
         <PDBx:auth_seq_num>8</PDBx:auth_seq_num>
         <PDBx:hetero>n</PDBx:hetero>
         <PDBx:ndb_seq_num>8</PDBx:ndb_seq_num>
         <PDBx:pdb_ins_code xsi:nil="true" />
         <PDBx:pdb_mon_id>CY3</PDBx:pdb_mon_id>
         <PDBx:pdb_seq_num>8</PDBx:pdb_seq_num>
         <PDBx:pdb_strand_id>A</PDBx:pdb_strand_id>
      </PDBx:pdbx_poly_seq_scheme>
   </PDBx:pdbx_poly_seq_schemeCategory>
   <PDBx:pdbx_struct_mod_residueCategory>
      <PDBx:pdbx_struct_mod_residue id="1">
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>HYP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:details>4-HYDROXYPROLINE</PDBx:details>
         <PDBx:label_asym_id>A</PDBx:label_asym_id>
         <PDBx:label_comp_id>HYP</PDBx:label_comp_id>
         <PDBx:label_seq_id>3</PDBx:label_seq_id>
         <PDBx:parent_comp_id>PRO</PDBx:parent_comp_id>
      </PDBx:pdbx_struct_mod_residue>
      <PDBx:pdbx_struct_mod_residue id="2">
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:details>D-TRYPTOPHAN</PDBx:details>
         <PDBx:label_asym_id>A</PDBx:label_asym_id>
         <PDBx:label_comp_id>DTR</PDBx:label_comp_id>
         <PDBx:label_seq_id>4</PDBx:label_seq_id>
         <PDBx:parent_comp_id>TRP</PDBx:parent_comp_id>
      </PDBx:pdbx_struct_mod_residue>
      <PDBx:pdbx_struct_mod_residue id="3">
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>CY3</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>8</PDBx:auth_seq_id>
         <PDBx:details>2-AMINO-3-MERCAPTO-PROPIONAMIDE</PDBx:details>
         <PDBx:label_asym_id>A</PDBx:label_asym_id>
         <PDBx:label_comp_id>CY3</PDBx:label_comp_id>
         <PDBx:label_seq_id>8</PDBx:label_seq_id>
         <PDBx:parent_comp_id>CYS</PDBx:parent_comp_id>
      </PDBx:pdbx_struct_mod_residue>
   </PDBx:pdbx_struct_mod_residueCategory>
   <PDBx:pdbx_validate_rmsd_angleCategory>
      <PDBx:pdbx_validate_rmsd_angle id="1">
         <PDBx:PDB_model_num>1</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-7.12</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>102.98</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="2">
         <PDBx:PDB_model_num>1</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.70</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>116.70</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="3">
         <PDBx:PDB_model_num>1</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.97</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>103.13</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="4">
         <PDBx:PDB_model_num>1</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.82</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>116.82</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="5">
         <PDBx:PDB_model_num>1</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.77</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>139.17</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="6">
         <PDBx:PDB_model_num>1</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.17</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>107.30</PDBx:angle_target_value>
         <PDBx:angle_value>101.13</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CD2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="7">
         <PDBx:PDB_model_num>2</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.52</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>103.58</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="8">
         <PDBx:PDB_model_num>2</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.28</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>117.28</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="9">
         <PDBx:PDB_model_num>2</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.97</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>139.37</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="10">
         <PDBx:PDB_model_num>2</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.45</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>107.30</PDBx:angle_target_value>
         <PDBx:angle_value>100.85</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CD2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="11">
         <PDBx:PDB_model_num>2</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.68</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>103.42</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="12">
         <PDBx:PDB_model_num>2</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.69</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>116.69</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="13">
         <PDBx:PDB_model_num>2</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.77</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>139.17</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="14">
         <PDBx:PDB_model_num>2</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.30</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>107.30</PDBx:angle_target_value>
         <PDBx:angle_value>101.00</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CD2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="15">
         <PDBx:PDB_model_num>3</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.69</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>103.41</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="16">
         <PDBx:PDB_model_num>3</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.98</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>116.98</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="17">
         <PDBx:PDB_model_num>3</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.43</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>137.83</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="18">
         <PDBx:PDB_model_num>3</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.98</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>103.12</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="19">
         <PDBx:PDB_model_num>3</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.05</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>117.05</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="20">
         <PDBx:PDB_model_num>3</PDBx:PDB_model_num>
         <PDBx:angle_deviation>9.12</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>139.52</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="21">
         <PDBx:PDB_model_num>3</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.35</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>107.30</PDBx:angle_target_value>
         <PDBx:angle_value>100.95</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CD2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="22">
         <PDBx:PDB_model_num>4</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-7.19</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>102.91</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="23">
         <PDBx:PDB_model_num>4</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.15</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>117.15</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="24">
         <PDBx:PDB_model_num>4</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.53</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>137.93</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="25">
         <PDBx:PDB_model_num>4</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.94</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>103.16</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="26">
         <PDBx:PDB_model_num>4</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.72</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>116.72</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="27">
         <PDBx:PDB_model_num>4</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.33</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>137.73</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="28">
         <PDBx:PDB_model_num>5</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-7.19</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>102.91</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="29">
         <PDBx:PDB_model_num>5</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.75</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>117.75</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="30">
         <PDBx:PDB_model_num>5</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.08</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>138.48</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="31">
         <PDBx:PDB_model_num>5</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.22</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>107.30</PDBx:angle_target_value>
         <PDBx:angle_value>101.08</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CD2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="32">
         <PDBx:PDB_model_num>5</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-7.01</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>103.09</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="33">
         <PDBx:PDB_model_num>5</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.36</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>117.36</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="34">
         <PDBx:PDB_model_num>5</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.97</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>139.37</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="35">
         <PDBx:PDB_model_num>5</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.29</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>107.30</PDBx:angle_target_value>
         <PDBx:angle_value>101.01</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CD2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="36">
         <PDBx:PDB_model_num>6</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.05</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>117.05</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="37">
         <PDBx:PDB_model_num>6</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.43</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>138.83</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="38">
         <PDBx:PDB_model_num>6</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-7.05</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>107.30</PDBx:angle_target_value>
         <PDBx:angle_value>100.25</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CD2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="39">
         <PDBx:PDB_model_num>6</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.47</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>103.63</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="40">
         <PDBx:PDB_model_num>6</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.98</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>116.98</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="41">
         <PDBx:PDB_model_num>6</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.09</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>137.49</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="42">
         <PDBx:PDB_model_num>6</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.66</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>107.30</PDBx:angle_target_value>
         <PDBx:angle_value>100.64</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CD2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="43">
         <PDBx:PDB_model_num>7</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-7.23</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>102.87</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="44">
         <PDBx:PDB_model_num>7</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.42</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>117.42</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="45">
         <PDBx:PDB_model_num>7</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.91</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>138.31</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="46">
         <PDBx:PDB_model_num>7</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.00</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>107.30</PDBx:angle_target_value>
         <PDBx:angle_value>101.30</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CD2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="47">
         <PDBx:PDB_model_num>7</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.98</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>103.12</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="48">
         <PDBx:PDB_model_num>7</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.18</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>117.18</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="49">
         <PDBx:PDB_model_num>7</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.50</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>138.90</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="50">
         <PDBx:PDB_model_num>7</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.47</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>107.30</PDBx:angle_target_value>
         <PDBx:angle_value>100.83</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CD2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="51">
         <PDBx:PDB_model_num>8</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-7.16</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>102.94</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="52">
         <PDBx:PDB_model_num>8</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.48</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>117.48</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="53">
         <PDBx:PDB_model_num>8</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.22</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>138.62</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="54">
         <PDBx:PDB_model_num>8</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.12</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>107.30</PDBx:angle_target_value>
         <PDBx:angle_value>101.18</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CD2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="55">
         <PDBx:PDB_model_num>8</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.62</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>116.62</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="56">
         <PDBx:PDB_model_num>8</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.36</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>137.76</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="57">
         <PDBx:PDB_model_num>9</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.83</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>103.27</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="58">
         <PDBx:PDB_model_num>9</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.06</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>117.06</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="59">
         <PDBx:PDB_model_num>9</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.19</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>137.59</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="60">
         <PDBx:PDB_model_num>9</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.93</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>103.17</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="61">
         <PDBx:PDB_model_num>9</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.94</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>116.94</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="62">
         <PDBx:PDB_model_num>9</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.66</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>139.06</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="63">
         <PDBx:PDB_model_num>9</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.22</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>107.30</PDBx:angle_target_value>
         <PDBx:angle_value>101.08</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CD2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="64">
         <PDBx:PDB_model_num>10</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-7.13</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>102.97</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="65">
         <PDBx:PDB_model_num>10</PDBx:PDB_model_num>
         <PDBx:angle_deviation>6.05</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>115.05</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="66">
         <PDBx:PDB_model_num>10</PDBx:PDB_model_num>
         <PDBx:angle_deviation>6.12</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>115.12</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="67">
         <PDBx:PDB_model_num>11</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-7.12</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>102.98</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="68">
         <PDBx:PDB_model_num>11</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.05</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>117.05</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="69">
         <PDBx:PDB_model_num>11</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.51</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>137.91</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="70">
         <PDBx:PDB_model_num>11</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-7.67</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>102.43</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="71">
         <PDBx:PDB_model_num>11</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.32</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>117.32</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="72">
         <PDBx:PDB_model_num>11</PDBx:PDB_model_num>
         <PDBx:angle_deviation>9.11</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>139.51</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="73">
         <PDBx:PDB_model_num>12</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-7.56</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>102.54</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="74">
         <PDBx:PDB_model_num>12</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.51</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>117.51</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="75">
         <PDBx:PDB_model_num>12</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.30</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>138.70</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="76">
         <PDBx:PDB_model_num>12</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-7.02</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>103.08</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="77">
         <PDBx:PDB_model_num>12</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.81</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>116.81</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="78">
         <PDBx:PDB_model_num>12</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.68</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>139.08</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="79">
         <PDBx:PDB_model_num>13</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.99</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>103.11</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="80">
         <PDBx:PDB_model_num>13</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.48</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>117.48</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="81">
         <PDBx:PDB_model_num>13</PDBx:PDB_model_num>
         <PDBx:angle_deviation>9.03</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>139.43</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="82">
         <PDBx:PDB_model_num>13</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.52</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>107.30</PDBx:angle_target_value>
         <PDBx:angle_value>100.78</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CD2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="83">
         <PDBx:PDB_model_num>13</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.91</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>103.19</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="84">
         <PDBx:PDB_model_num>13</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.96</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>116.96</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="85">
         <PDBx:PDB_model_num>13</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.87</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>138.27</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="86">
         <PDBx:PDB_model_num>13</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.09</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>107.30</PDBx:angle_target_value>
         <PDBx:angle_value>101.21</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CD2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="87">
         <PDBx:PDB_model_num>14</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.99</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>103.11</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="88">
         <PDBx:PDB_model_num>14</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.21</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>117.21</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="89">
         <PDBx:PDB_model_num>14</PDBx:PDB_model_num>
         <PDBx:angle_deviation>6.99</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>137.39</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="90">
         <PDBx:PDB_model_num>14</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.43</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>103.67</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="91">
         <PDBx:PDB_model_num>14</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.53</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>116.53</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="92">
         <PDBx:PDB_model_num>14</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.13</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>138.53</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="93">
         <PDBx:PDB_model_num>14</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.00</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>107.30</PDBx:angle_target_value>
         <PDBx:angle_value>101.30</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CD2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="94">
         <PDBx:PDB_model_num>15</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.65</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>103.45</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="95">
         <PDBx:PDB_model_num>15</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.93</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>116.93</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="96">
         <PDBx:PDB_model_num>15</PDBx:PDB_model_num>
         <PDBx:angle_deviation>6.85</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>137.25</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="97">
         <PDBx:PDB_model_num>15</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.74</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>103.36</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="98">
         <PDBx:PDB_model_num>15</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.34</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>117.34</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="99">
         <PDBx:PDB_model_num>15</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.12</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>138.52</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="100">
         <PDBx:PDB_model_num>15</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.44</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>107.30</PDBx:angle_target_value>
         <PDBx:angle_value>100.86</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CD2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="101">
         <PDBx:PDB_model_num>16</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-7.15</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>102.95</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="102">
         <PDBx:PDB_model_num>16</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.14</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>117.14</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="103">
         <PDBx:PDB_model_num>16</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.84</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>138.24</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="104">
         <PDBx:PDB_model_num>16</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.12</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>107.30</PDBx:angle_target_value>
         <PDBx:angle_value>101.18</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CD2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="105">
         <PDBx:PDB_model_num>16</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.44</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>103.66</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="106">
         <PDBx:PDB_model_num>16</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.52</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>116.52</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="107">
         <PDBx:PDB_model_num>16</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.49</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>138.89</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="108">
         <PDBx:PDB_model_num>16</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.00</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>107.30</PDBx:angle_target_value>
         <PDBx:angle_value>101.30</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CD2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="109">
         <PDBx:PDB_model_num>17</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-7.16</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>102.94</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="110">
         <PDBx:PDB_model_num>17</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.80</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>116.80</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="111">
         <PDBx:PDB_model_num>17</PDBx:PDB_model_num>
         <PDBx:angle_deviation>6.64</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>137.04</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="112">
         <PDBx:PDB_model_num>17</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.75</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>103.35</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="113">
         <PDBx:PDB_model_num>17</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.54</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>117.54</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="114">
         <PDBx:PDB_model_num>17</PDBx:PDB_model_num>
         <PDBx:angle_deviation>9.48</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>139.88</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="115">
         <PDBx:PDB_model_num>18</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.79</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>103.31</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="116">
         <PDBx:PDB_model_num>18</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.00</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>117.00</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="117">
         <PDBx:PDB_model_num>18</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.45</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>137.85</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="118">
         <PDBx:PDB_model_num>18</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.63</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>103.47</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="119">
         <PDBx:PDB_model_num>18</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.89</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>116.89</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="120">
         <PDBx:PDB_model_num>18</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.07</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>138.47</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="121">
         <PDBx:PDB_model_num>18</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.25</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>107.30</PDBx:angle_target_value>
         <PDBx:angle_value>101.05</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CD2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="122">
         <PDBx:PDB_model_num>19</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.50</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>103.60</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="123">
         <PDBx:PDB_model_num>19</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.25</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>117.25</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="124">
         <PDBx:PDB_model_num>19</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.53</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>137.93</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="125">
         <PDBx:PDB_model_num>19</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.31</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>103.79</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="126">
         <PDBx:PDB_model_num>19</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.60</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>116.60</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="127">
         <PDBx:PDB_model_num>19</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.10</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>137.50</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="128">
         <PDBx:PDB_model_num>20</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.27</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>103.83</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="129">
         <PDBx:PDB_model_num>20</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.62</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>116.62</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="130">
         <PDBx:PDB_model_num>20</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.59</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>138.99</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="131">
         <PDBx:PDB_model_num>20</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.23</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>107.30</PDBx:angle_target_value>
         <PDBx:angle_value>101.07</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CD2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>DTR</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>4</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="132">
         <PDBx:PDB_model_num>20</PDBx:PDB_model_num>
         <PDBx:angle_deviation>-6.96</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.00</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>110.10</PDBx:angle_target_value>
         <PDBx:angle_value>103.14</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>NE1</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="133">
         <PDBx:PDB_model_num>20</PDBx:PDB_model_num>
         <PDBx:angle_deviation>8.05</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>0.90</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>109.00</PDBx:angle_target_value>
         <PDBx:angle_value>117.05</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>CD1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>NE1</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CE2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
      <PDBx:pdbx_validate_rmsd_angle id="134">
         <PDBx:PDB_model_num>20</PDBx:PDB_model_num>
         <PDBx:angle_deviation>7.32</PDBx:angle_deviation>
         <PDBx:angle_standard_deviation>1.10</PDBx:angle_standard_deviation>
         <PDBx:angle_target_value>130.40</PDBx:angle_target_value>
         <PDBx:angle_value>137.72</PDBx:angle_value>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_asym_id_3>A</PDBx:auth_asym_id_3>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_atom_id_3>CZ2</PDBx:auth_atom_id_3>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_comp_id_3>TRP</PDBx:auth_comp_id_3>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:auth_seq_id_3>7</PDBx:auth_seq_id_3>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_angle>
   </PDBx:pdbx_validate_rmsd_angleCategory>
   <PDBx:pdbx_validate_rmsd_bondCategory>
      <PDBx:pdbx_validate_rmsd_bond id="1">
         <PDBx:PDB_model_num>1</PDBx:PDB_model_num>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD2</PDBx:auth_atom_id_2>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:bond_deviation>-0.112</PDBx:bond_deviation>
         <PDBx:bond_standard_deviation>0.017</PDBx:bond_standard_deviation>
         <PDBx:bond_target_value>1.432</PDBx:bond_target_value>
         <PDBx:bond_value>1.320</PDBx:bond_value>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_bond>
      <PDBx:pdbx_validate_rmsd_bond id="2">
         <PDBx:PDB_model_num>10</PDBx:PDB_model_num>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_atom_id_1>CG</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CD2</PDBx:auth_atom_id_2>
         <PDBx:auth_comp_id_1>DTR</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>DTR</PDBx:auth_comp_id_2>
         <PDBx:auth_seq_id_1>4</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>4</PDBx:auth_seq_id_2>
         <PDBx:bond_deviation>-0.115</PDBx:bond_deviation>
         <PDBx:bond_standard_deviation>0.017</PDBx:bond_standard_deviation>
         <PDBx:bond_target_value>1.432</PDBx:bond_target_value>
         <PDBx:bond_value>1.317</PDBx:bond_value>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_bond>
      <PDBx:pdbx_validate_rmsd_bond id="3">
         <PDBx:PDB_model_num>17</PDBx:PDB_model_num>
         <PDBx:auth_asym_id_1>A</PDBx:auth_asym_id_1>
         <PDBx:auth_asym_id_2>A</PDBx:auth_asym_id_2>
         <PDBx:auth_atom_id_1>NE1</PDBx:auth_atom_id_1>
         <PDBx:auth_atom_id_2>CE2</PDBx:auth_atom_id_2>
         <PDBx:auth_comp_id_1>TRP</PDBx:auth_comp_id_1>
         <PDBx:auth_comp_id_2>TRP</PDBx:auth_comp_id_2>
         <PDBx:auth_seq_id_1>7</PDBx:auth_seq_id_1>
         <PDBx:auth_seq_id_2>7</PDBx:auth_seq_id_2>
         <PDBx:bond_deviation>-0.079</PDBx:bond_deviation>
         <PDBx:bond_standard_deviation>0.013</PDBx:bond_standard_deviation>
         <PDBx:bond_target_value>1.371</PDBx:bond_target_value>
         <PDBx:bond_value>1.292</PDBx:bond_value>
         <PDBx:linker_flag>N</PDBx:linker_flag>
      </PDBx:pdbx_validate_rmsd_bond>
   </PDBx:pdbx_validate_rmsd_bondCategory>
   <PDBx:pdbx_validate_torsionCategory>
      <PDBx:pdbx_validate_torsion id="1">
         <PDBx:PDB_model_num>1</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>CYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>2</PDBx:auth_seq_id>
         <PDBx:phi>-124.48</PDBx:phi>
         <PDBx:psi>-169.33</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="2">
         <PDBx:PDB_model_num>1</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>91.15</PDBx:phi>
         <PDBx:psi>-59.05</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="3">
         <PDBx:PDB_model_num>1</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>PRO</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>6</PDBx:auth_seq_id>
         <PDBx:phi>-70.12</PDBx:phi>
         <PDBx:psi>-72.80</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="4">
         <PDBx:PDB_model_num>1</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>TRP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>7</PDBx:auth_seq_id>
         <PDBx:phi>-45.84</PDBx:phi>
         <PDBx:psi>87.81</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="5">
         <PDBx:PDB_model_num>2</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>91.14</PDBx:phi>
         <PDBx:psi>-53.63</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="6">
         <PDBx:PDB_model_num>2</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>TRP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>7</PDBx:auth_seq_id>
         <PDBx:phi>-54.38</PDBx:phi>
         <PDBx:psi>91.19</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="7">
         <PDBx:PDB_model_num>3</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>HYP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:phi>-60.65</PDBx:phi>
         <PDBx:psi>99.35</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="8">
         <PDBx:PDB_model_num>3</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>91.13</PDBx:phi>
         <PDBx:psi>-52.61</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="9">
         <PDBx:PDB_model_num>3</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>TRP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>7</PDBx:auth_seq_id>
         <PDBx:phi>-57.55</PDBx:phi>
         <PDBx:psi>69.34</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="10">
         <PDBx:PDB_model_num>4</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>HYP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:phi>-41.99</PDBx:phi>
         <PDBx:psi>91.28</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="11">
         <PDBx:PDB_model_num>4</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>90.90</PDBx:phi>
         <PDBx:psi>-55.47</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="12">
         <PDBx:PDB_model_num>5</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>CYS</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>2</PDBx:auth_seq_id>
         <PDBx:phi>-110.60</PDBx:phi>
         <PDBx:psi>-163.95</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="13">
         <PDBx:PDB_model_num>5</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>HYP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:phi>-64.67</PDBx:phi>
         <PDBx:psi>89.96</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="14">
         <PDBx:PDB_model_num>5</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>91.02</PDBx:phi>
         <PDBx:psi>-42.74</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="15">
         <PDBx:PDB_model_num>6</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>90.42</PDBx:phi>
         <PDBx:psi>-50.64</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="16">
         <PDBx:PDB_model_num>6</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>TRP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>7</PDBx:auth_seq_id>
         <PDBx:phi>-65.44</PDBx:phi>
         <PDBx:psi>85.05</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="17">
         <PDBx:PDB_model_num>7</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>HYP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:phi>-57.68</PDBx:phi>
         <PDBx:psi>97.72</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="18">
         <PDBx:PDB_model_num>7</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>90.94</PDBx:phi>
         <PDBx:psi>-47.25</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="19">
         <PDBx:PDB_model_num>7</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>TRP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>7</PDBx:auth_seq_id>
         <PDBx:phi>-62.98</PDBx:phi>
         <PDBx:psi>81.38</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="20">
         <PDBx:PDB_model_num>8</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>HYP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:phi>-54.45</PDBx:phi>
         <PDBx:psi>103.00</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="21">
         <PDBx:PDB_model_num>8</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>90.50</PDBx:phi>
         <PDBx:psi>-50.54</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="22">
         <PDBx:PDB_model_num>9</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>HYP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:phi>-46.65</PDBx:phi>
         <PDBx:psi>91.44</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="23">
         <PDBx:PDB_model_num>9</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>90.64</PDBx:phi>
         <PDBx:psi>-55.28</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="24">
         <PDBx:PDB_model_num>10</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>90.45</PDBx:phi>
         <PDBx:psi>-52.81</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="25">
         <PDBx:PDB_model_num>10</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>TRP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>7</PDBx:auth_seq_id>
         <PDBx:phi>-57.05</PDBx:phi>
         <PDBx:psi>90.39</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="26">
         <PDBx:PDB_model_num>11</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>91.90</PDBx:phi>
         <PDBx:psi>-54.50</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="27">
         <PDBx:PDB_model_num>12</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>91.43</PDBx:phi>
         <PDBx:psi>-54.68</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="28">
         <PDBx:PDB_model_num>12</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>TRP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>7</PDBx:auth_seq_id>
         <PDBx:phi>-69.26</PDBx:phi>
         <PDBx:psi>91.70</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="29">
         <PDBx:PDB_model_num>13</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>HYP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:phi>-30.96</PDBx:phi>
         <PDBx:psi>77.00</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="30">
         <PDBx:PDB_model_num>13</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>90.51</PDBx:phi>
         <PDBx:psi>-41.34</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="31">
         <PDBx:PDB_model_num>14</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>HYP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:phi>-47.55</PDBx:phi>
         <PDBx:psi>87.18</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="32">
         <PDBx:PDB_model_num>14</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>90.40</PDBx:phi>
         <PDBx:psi>-43.82</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="33">
         <PDBx:PDB_model_num>15</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>HYP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:phi>-55.13</PDBx:phi>
         <PDBx:psi>93.45</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="34">
         <PDBx:PDB_model_num>15</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>90.79</PDBx:phi>
         <PDBx:psi>-44.26</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="35">
         <PDBx:PDB_model_num>15</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>TRP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>7</PDBx:auth_seq_id>
         <PDBx:phi>-55.63</PDBx:phi>
         <PDBx:psi>109.24</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="36">
         <PDBx:PDB_model_num>16</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>HYP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:phi>-41.42</PDBx:phi>
         <PDBx:psi>102.59</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="37">
         <PDBx:PDB_model_num>16</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>91.69</PDBx:phi>
         <PDBx:psi>-47.36</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="38">
         <PDBx:PDB_model_num>16</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>TRP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>7</PDBx:auth_seq_id>
         <PDBx:phi>-52.97</PDBx:phi>
         <PDBx:psi>80.31</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="39">
         <PDBx:PDB_model_num>17</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>HYP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:phi>-58.42</PDBx:phi>
         <PDBx:psi>109.61</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="40">
         <PDBx:PDB_model_num>17</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>90.59</PDBx:phi>
         <PDBx:psi>-51.55</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="41">
         <PDBx:PDB_model_num>17</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>TRP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>7</PDBx:auth_seq_id>
         <PDBx:phi>-63.09</PDBx:phi>
         <PDBx:psi>60.91</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="42">
         <PDBx:PDB_model_num>18</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>92.84</PDBx:phi>
         <PDBx:psi>-54.41</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="43">
         <PDBx:PDB_model_num>18</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>TRP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>7</PDBx:auth_seq_id>
         <PDBx:phi>-61.79</PDBx:phi>
         <PDBx:psi>76.94</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="44">
         <PDBx:PDB_model_num>19</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>HYP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:phi>-47.94</PDBx:phi>
         <PDBx:psi>89.70</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="45">
         <PDBx:PDB_model_num>19</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>93.04</PDBx:phi>
         <PDBx:psi>-45.11</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="46">
         <PDBx:PDB_model_num>20</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>HYP</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>3</PDBx:auth_seq_id>
         <PDBx:phi>-41.63</PDBx:phi>
         <PDBx:psi>108.53</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
      <PDBx:pdbx_validate_torsion id="47">
         <PDBx:PDB_model_num>20</PDBx:PDB_model_num>
         <PDBx:auth_asym_id>A</PDBx:auth_asym_id>
         <PDBx:auth_comp_id>DTR</PDBx:auth_comp_id>
         <PDBx:auth_seq_id>4</PDBx:auth_seq_id>
         <PDBx:phi>91.10</PDBx:phi>
         <PDBx:psi>-54.08</PDBx:psi>
      </PDBx:pdbx_validate_torsion>
   </PDBx:pdbx_validate_torsionCategory>
   <PDBx:structCategory>
      <PDBx:struct entry_id="1DFZ">
         <PDBx:pdbx_descriptor>CONTRYPHAN-SM</PDBx:pdbx_descriptor>
         <PDBx:title>NMR STRUCTURE OF CONTRYPHAN-SM CYCLIC PEPTIDE (MINOR FORM-TRANS)</PDBx:title>
      </PDBx:struct>
   </PDBx:structCategory>
   <PDBx:struct_asymCategory>
      <PDBx:struct_asym id="A">
         <PDBx:entity_id>1</PDBx:entity_id>
         <PDBx:pdbx_blank_PDB_chainid_flag>N</PDBx:pdbx_blank_PDB_chainid_flag>
         <PDBx:pdbx_modified>N</PDBx:pdbx_modified>
      </PDBx:struct_asym>
   </PDBx:struct_asymCategory>
   <PDBx:struct_biolCategory>
      <PDBx:struct_biol id="1"></PDBx:struct_biol>
   </PDBx:struct_biolCategory>
   <PDBx:struct_connCategory>
      <PDBx:struct_conn id="covale1">
         <PDBx:conn_type_id>covale</PDBx:conn_type_id>
         <PDBx:pdbx_dist_value>1.312</PDBx:pdbx_dist_value>
         <PDBx:ptnr1_auth_asym_id>A</PDBx:ptnr1_auth_asym_id>
         <PDBx:ptnr1_auth_comp_id>CYS</PDBx:ptnr1_auth_comp_id>
         <PDBx:ptnr1_auth_seq_id>2</PDBx:ptnr1_auth_seq_id>
         <PDBx:ptnr1_label_asym_id>A</PDBx:ptnr1_label_asym_id>
         <PDBx:ptnr1_label_atom_id>C</PDBx:ptnr1_label_atom_id>
         <PDBx:ptnr1_label_comp_id>CYS</PDBx:ptnr1_label_comp_id>
         <PDBx:ptnr1_label_seq_id>2</PDBx:ptnr1_label_seq_id>
         <PDBx:ptnr1_symmetry>1_555</PDBx:ptnr1_symmetry>
         <PDBx:ptnr2_auth_asym_id>A</PDBx:ptnr2_auth_asym_id>
         <PDBx:ptnr2_auth_comp_id>HYP</PDBx:ptnr2_auth_comp_id>
         <PDBx:ptnr2_auth_seq_id>3</PDBx:ptnr2_auth_seq_id>
         <PDBx:ptnr2_label_asym_id>A</PDBx:ptnr2_label_asym_id>
         <PDBx:ptnr2_label_atom_id>N</PDBx:ptnr2_label_atom_id>
         <PDBx:ptnr2_label_comp_id>HYP</PDBx:ptnr2_label_comp_id>
         <PDBx:ptnr2_label_seq_id>3</PDBx:ptnr2_label_seq_id>
         <PDBx:ptnr2_symmetry>1_555</PDBx:ptnr2_symmetry>
      </PDBx:struct_conn>
      <PDBx:struct_conn id="covale2">
         <PDBx:conn_type_id>covale</PDBx:conn_type_id>
         <PDBx:pdbx_dist_value>2.022</PDBx:pdbx_dist_value>
         <PDBx:ptnr1_auth_asym_id>A</PDBx:ptnr1_auth_asym_id>
         <PDBx:ptnr1_auth_comp_id>CYS</PDBx:ptnr1_auth_comp_id>
         <PDBx:ptnr1_auth_seq_id>2</PDBx:ptnr1_auth_seq_id>
         <PDBx:ptnr1_label_asym_id>A</PDBx:ptnr1_label_asym_id>
         <PDBx:ptnr1_label_atom_id>SG</PDBx:ptnr1_label_atom_id>
         <PDBx:ptnr1_label_comp_id>CYS</PDBx:ptnr1_label_comp_id>
         <PDBx:ptnr1_label_seq_id>2</PDBx:ptnr1_label_seq_id>
         <PDBx:ptnr1_symmetry>1_555</PDBx:ptnr1_symmetry>
         <PDBx:ptnr2_auth_asym_id>A</PDBx:ptnr2_auth_asym_id>
         <PDBx:ptnr2_auth_comp_id>CY3</PDBx:ptnr2_auth_comp_id>
         <PDBx:ptnr2_auth_seq_id>8</PDBx:ptnr2_auth_seq_id>
         <PDBx:ptnr2_label_asym_id>A</PDBx:ptnr2_label_asym_id>
         <PDBx:ptnr2_label_atom_id>SG</PDBx:ptnr2_label_atom_id>
         <PDBx:ptnr2_label_comp_id>CY3</PDBx:ptnr2_label_comp_id>
         <PDBx:ptnr2_label_seq_id>8</PDBx:ptnr2_label_seq_id>
         <PDBx:ptnr2_symmetry>1_555</PDBx:ptnr2_symmetry>
      </PDBx:struct_conn>
      <PDBx:struct_conn id="covale3">
         <PDBx:conn_type_id>covale</PDBx:conn_type_id>
         <PDBx:pdbx_dist_value>1.306</PDBx:pdbx_dist_value>
         <PDBx:ptnr1_auth_asym_id>A</PDBx:ptnr1_auth_asym_id>
         <PDBx:ptnr1_auth_comp_id>HYP</PDBx:ptnr1_auth_comp_id>
         <PDBx:ptnr1_auth_seq_id>3</PDBx:ptnr1_auth_seq_id>
         <PDBx:ptnr1_label_asym_id>A</PDBx:ptnr1_label_asym_id>
         <PDBx:ptnr1_label_atom_id>C</PDBx:ptnr1_label_atom_id>
         <PDBx:ptnr1_label_comp_id>HYP</PDBx:ptnr1_label_comp_id>
         <PDBx:ptnr1_label_seq_id>3</PDBx:ptnr1_label_seq_id>
         <PDBx:ptnr1_symmetry>1_555</PDBx:ptnr1_symmetry>
         <PDBx:ptnr2_auth_asym_id>A</PDBx:ptnr2_auth_asym_id>
         <PDBx:ptnr2_auth_comp_id>DTR</PDBx:ptnr2_auth_comp_id>
         <PDBx:ptnr2_auth_seq_id>4</PDBx:ptnr2_auth_seq_id>
         <PDBx:ptnr2_label_asym_id>A</PDBx:ptnr2_label_asym_id>
         <PDBx:ptnr2_label_atom_id>N</PDBx:ptnr2_label_atom_id>
         <PDBx:ptnr2_label_comp_id>DTR</PDBx:ptnr2_label_comp_id>
         <PDBx:ptnr2_label_seq_id>4</PDBx:ptnr2_label_seq_id>
         <PDBx:ptnr2_symmetry>1_555</PDBx:ptnr2_symmetry>
      </PDBx:struct_conn>
      <PDBx:struct_conn id="covale4">
         <PDBx:conn_type_id>covale</PDBx:conn_type_id>
         <PDBx:pdbx_dist_value>1.297</PDBx:pdbx_dist_value>
         <PDBx:ptnr1_auth_asym_id>A</PDBx:ptnr1_auth_asym_id>
         <PDBx:ptnr1_auth_comp_id>DTR</PDBx:ptnr1_auth_comp_id>
         <PDBx:ptnr1_auth_seq_id>4</PDBx:ptnr1_auth_seq_id>
         <PDBx:ptnr1_label_asym_id>A</PDBx:ptnr1_label_asym_id>
         <PDBx:ptnr1_label_atom_id>C</PDBx:ptnr1_label_atom_id>
         <PDBx:ptnr1_label_comp_id>DTR</PDBx:ptnr1_label_comp_id>
         <PDBx:ptnr1_label_seq_id>4</PDBx:ptnr1_label_seq_id>
         <PDBx:ptnr1_symmetry>1_555</PDBx:ptnr1_symmetry>
         <PDBx:ptnr2_auth_asym_id>A</PDBx:ptnr2_auth_asym_id>
         <PDBx:ptnr2_auth_comp_id>GLN</PDBx:ptnr2_auth_comp_id>
         <PDBx:ptnr2_auth_seq_id>5</PDBx:ptnr2_auth_seq_id>
         <PDBx:ptnr2_label_asym_id>A</PDBx:ptnr2_label_asym_id>
         <PDBx:ptnr2_label_atom_id>N</PDBx:ptnr2_label_atom_id>
         <PDBx:ptnr2_label_comp_id>GLN</PDBx:ptnr2_label_comp_id>
         <PDBx:ptnr2_label_seq_id>5</PDBx:ptnr2_label_seq_id>
         <PDBx:ptnr2_symmetry>1_555</PDBx:ptnr2_symmetry>
      </PDBx:struct_conn>
      <PDBx:struct_conn id="covale5">
         <PDBx:conn_type_id>covale</PDBx:conn_type_id>
         <PDBx:pdbx_dist_value>1.300</PDBx:pdbx_dist_value>
         <PDBx:ptnr1_auth_asym_id>A</PDBx:ptnr1_auth_asym_id>
         <PDBx:ptnr1_auth_comp_id>TRP</PDBx:ptnr1_auth_comp_id>
         <PDBx:ptnr1_auth_seq_id>7</PDBx:ptnr1_auth_seq_id>
         <PDBx:ptnr1_label_asym_id>A</PDBx:ptnr1_label_asym_id>
         <PDBx:ptnr1_label_atom_id>C</PDBx:ptnr1_label_atom_id>
         <PDBx:ptnr1_label_comp_id>TRP</PDBx:ptnr1_label_comp_id>
         <PDBx:ptnr1_label_seq_id>7</PDBx:ptnr1_label_seq_id>
         <PDBx:ptnr1_symmetry>1_555</PDBx:ptnr1_symmetry>
         <PDBx:ptnr2_auth_asym_id>A</PDBx:ptnr2_auth_asym_id>
         <PDBx:ptnr2_auth_comp_id>CY3</PDBx:ptnr2_auth_comp_id>
         <PDBx:ptnr2_auth_seq_id>8</PDBx:ptnr2_auth_seq_id>
         <PDBx:ptnr2_label_asym_id>A</PDBx:ptnr2_label_asym_id>
         <PDBx:ptnr2_label_atom_id>N</PDBx:ptnr2_label_atom_id>
         <PDBx:ptnr2_label_comp_id>CY3</PDBx:ptnr2_label_comp_id>
         <PDBx:ptnr2_label_seq_id>8</PDBx:ptnr2_label_seq_id>
         <PDBx:ptnr2_symmetry>1_555</PDBx:ptnr2_symmetry>
      </PDBx:struct_conn>
   </PDBx:struct_connCategory>
   <PDBx:struct_conn_typeCategory>
      <PDBx:struct_conn_type id="covale">
      </PDBx:struct_conn_type>
   </PDBx:struct_conn_typeCategory>
   <PDBx:struct_keywordsCategory>
      <PDBx:struct_keywords entry_id="1DFZ">
         <PDBx:pdbx_keywords>TOXIN</PDBx:pdbx_keywords>
         <PDBx:text>CYCLIC PEPTIDE, DISULFIDE BRIDGE, D-TRYPTOPHAN, CIS-TRANS ISOMERISM, CONTRYPHAN, TOXIN</PDBx:text>
      </PDBx:struct_keywords>
   </PDBx:struct_keywordsCategory>
   <PDBx:symmetryCategory>
      <PDBx:symmetry entry_id="1DFZ">
         <PDBx:Int_Tables_number>1</PDBx:Int_Tables_number>
         <PDBx:space_group_name_H-M>P 1</PDBx:space_group_name_H-M>
      </PDBx:symmetry>
   </PDBx:symmetryCategory>
</PDBx:datablock>
